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Find a pnc business banker near you. Find a convenient time to meet with us. Whether you are a current customer and have a question, or you're a new one and want to learn more, we're. Call the pnc customer service line that best suits your needs. Enter your account number or credit card number, or say โi donโt have it. โ press the number corresponding to your. There are two different phone numbers for contacting pnc customer support. Hereโs how you can contact pnc customer service by: How to call pnc customer service. To inquire about general info, you can dial one of the following.